California State University Long
Beach

GEOL 300i; Earth Systems and Global Change
Lecture 8

The Hydrosphere
Nature and composition
- Water vapor from outgassing (with other volatiles)
- Condensation to:
- Rain & snow (precipitation)
- Runoff leads to:
- Lakes, rivers, oceans, pore waters, ice sheets
& glaciers
- Early meteoric water (rain & surface/ocean water)
- May have been strongly acidic from dissolved:
- Sulfurous gases
- Weathering may have been more rapid on young
Earth
- Accumulation of salts in oceans due to
weathering
- Modern hydrosphere (different %'s by different methods).
- 80% (96%) seawater.
- 18% in lithosphere
- (~2%) Porewater (mostly seawater in sediments)
- ~16% Bound water in minerals
- ~2% (~2%) glacial ice
- Ice sheets
- Alpine glaciers
- 1% in fresh surface water & atmospheric
water vapor
.
The water cycle or "hydrologic cycle"
- Evaporation to atmosphere
- Transport within atmosphere
- Condensation/Precipitation
- Overland & underground transport
- Accumulation in lakes, oceans, & groundwater
The hydrologic cycle:
- Most important
agent of transfer between systems (reservoirs)
- Circulates matter
- H2O
- Dissolved ions and compounds
- Exchanges and redistributes energy
- Heat, evaporation, condensation
- Residence time
- Atmosphere contains 0.015 X 106 km3
H2O
- Evaporation from oceans and land = 0.5 X 106
km3 H2O/year
- Residence time = size of reservoir / input rate
- Residence time of water in atmosphere = 0.03
years = 11 days
The Water Molecule
- Structure:
- Two hydrogen molecules "bending"
to one side of oxygen
- Polar molecule
- Physical Properties
- Unusual because
polar structure of water molecule causes hydrogen bonding
- All three physical states (solid, liquid, gas)
on Earth
- Odd melting and boiling points
- High heat capacity
- Strong solvent (can easily dissolve other
things)
- Density (solid is less dense than liquid)
Seawater
- Important differences in physical properties and chemistry from
fresh water
- With addition of salts (ie. in seawater), properties are modified:
- Major ions:
- Cl-, Na+, SO4-2,
Mg+2, Ca+2, K+, HCO3-
- pH approximately 8.0
- Density of seawater density of freshwater
- Density of freshwater = 1.000 gm/cm3
- Density of seawater = 1.027; gm/cm3
- SW freezes at lower temperature than FW
- Freshwater freezes at 0 degrees C
- Typical seawater freezes at -1.9 degrees C
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Phone: 562-985-4928
written by R. Behl.
Last changes: 25 Sept 1997